Compositional diversity in insoluble organic matter in type 1, 2 and 3 chondrites as detected by infrared spectroscopy     

Yoko Kebukawa  Conel M.O’D. Alexander 《Geochimica et cosmochimica acta》2011,75(12):3530-3541

Insoluble organic matter (IOM) isolated from 22 carbonaceous and ordinary chondrites spanning a wide range of groups and petrologic types were analyzed using Fourier transform infrared spectroscopy (FTIR). Based on common IR spectral features, it is observed that IOM falls into 4 molecularly distinct groups (designated here as A through D). Spectral group A includes type 1 and 2 chondrites and exhibits intense aliphatic C-H and carboxyl vibrational peaks. Spectral group B includes the least metamorphosed type 3 chondrites and Tagish Lake, and exhibits weaker aliphatic and carboxyl vibrational intensity. Spectral groups C and D include metamorphosed type ?3.1 chondrites and a heated CM chondrite. The carbonyl stretching features in spectral groups C and D differ from that in spectral groups A and B and from each other. In spectral group C, the carbonyl stretching is assigned to cyclic unsaturated lactones; in spectral group D carbonyl exists predominantly in the form of unsaturated ketone moieties. Both spectral groups C and D have a relatively narrow band structure around 1210 cm⁻¹ (assigned to aromatic skeletal modes) as compared with spectral groups A and B, which is consistent with the formation of more condensed aromatics by extensive thermal metamorphism. The differences in carbonyl structures in spectral groups C and D are not the result of different effective metamorphic temperatures, rather these differences likely result from variation in the activity of water and oxygen at different stages of parent body metamorphism. Such environmental variations must be local phenomena in the parent bodies as there is no correlation between spectral grouping and chondrite class or group.  相似文献   

Importance of instantaneous radiative forcing for rapid tropospheric adjustment     

Tomoo Ogura  Mark J. Webb  Masahiro Watanabe  F. Hugo Lambert  Yoko Tsushima  Miho Sekiguchi 《Climate Dynamics》2014,43(5-6):1409-1421

To better understand CFMIP/CMIP inter-model differences in rapid low cloud responses to CO₂ increases and their associated effective radiative forcings, we examined the tropospheric adjustment of the lower tropospheric stability (LTS) in three general circulation models (GCMs): HadGEM2-A, MIROC3.2 medres, and MIROC5. MIROC3.2 medres showed a reduction in LTS over the sub-tropical ocean, in contrast to the other two models. This reduction was consistent with a temperature decrease in the mid-troposphere. The temperature decrease was mainly driven by instantaneous radiative forcing (RF) caused by an increase in CO₂. Reductions in radiative and latent heating, due to clouds, and in adiabatic and advective heating, also contribute to the temperature decrease. The instantaneous RF in the mid-troposphere in MIROC3.2 medres is inconsistent with the results of line-by-line (LBL) calculations, and thus it is considered questionable. These results illustrate the importance of evaluating the vertical profile of instantaneous RF with LBL calculations; improved future model performance in this regard should help to increase our confidence in the tropospheric adjustment in GCMs.  相似文献   

Synoptic weather conditions and aerosol episodes over Indo-Gangetic Plains,India     

D. G. Kaskaoutis  E. E. Houssos  D. Goto  A. Bartzokas  P. T. Nastos  P. R. Sinha  S. K. Kharol  P. G. Kosmopoulos  R. P. Singh  T. Takemura 《Climate Dynamics》2014,43(9-10):2313-2331

The present study focuses on identifying the main atmospheric circulation characteristics associated with aerosol episodes (AEs) over Kanpur, India during the period 2001–2010. In this respect, mean sea level pressure (MSLP) and geopotential height of 700 hPa (Z700) data obtained from the NCEP/NCAR Reanalysis Project were used along with daily Terra-MODIS AOD₅₅₀ data. The analysis identifies 277 AEs [AOD₅₀₀ >  \( \overline{AOD} \) ₅₀₀ + 1STDEV (standard deviation)] over Kanpur corresponding to 13.2 % of the available AERONET dataset, which are seasonally distributed as 12.5, 9.1, 14.7 and 18.6 % for winter (Dec–Feb), pre-monsoon (Mar–May), monsoon (Jun–Sep) and post-monsoon (Oct–Nov), respectively. The post-monsoon and winter AEs are mostly related to anthropogenic emissions, in contrast to pre-monsoon and monsoon episodes when a significant component of dust is found. The multivariate statistical methods Factor and Cluster Analysis are applied on the dataset of the AEs days’ Z700 patterns over south Asia, to group them into discrete clusters. Six clusters are identified and for each of them the composite means for MSLP and Z700 as well as their anomalies from the mean 1981–2010 climatology are studied. Furthermore, the spatial distribution of Terra-MODIS AOD₅₅₀ over Indian sub-continent is examined to identify aerosol hot-spot areas for each cluster, while the SPRINTARS model simulations reveal incapability in reproducing the large anthropogenic AOD, suggesting need of further improvement in model emission inventories. This work is the first performed over India aiming to analyze and group the atmospheric circulation patterns associated with AEs over Indo-Gangetic Plains and to explore the influence of meteorology on the accumulation of aerosols.  相似文献   

Comparison of FT‐IR spectra of bulk and acid insoluble organic matter in chondritic meteorites: An implication for missing carbon during demineralization     

Yoko Kebukawa  Conel M. O'D. Alexander  George D. Cody 《Meteoritics & planetary science》2019,54(7):1632-1641

Past studies of the various separable carbonaceous fractions have been unable to account for all of C in primitive chondrites. In particular, up to 20–50% of the C is lost during acid leaching of bulk samples even after the C in carbonates and soluble organic matter is accounted for. To try to better characterize the nature of this “missing C,” we have compared the bulk infrared (IR) absorption spectra of a number of primitive chondrites with those of their previously reported insoluble organic matter (IOM). The aliphatic C–H stretching bands, in particular, allow us to compare the molecular structures of bulk C with that of IOM. The spectral differences between bulk C and IOM reflect “missing C” phases that were lost during acid leaching, although we cannot completely exclude the possibility that the OM was modified after demineralization. Comparing IR spectra of bulk meteorite powder and IOM suggests that the missing C varies in its molecular structure, and that mildly thermally metamorphosed type 3 chondrites tend to be richer in an aliphatic fraction with lower CH₂/CH₃ ratios, relative to IOM, compared to aqueously altered carbonaceous chondrites (CI/CM/CR). The missing C is most likely released from acid‐labile functional groups, such as esters, acetals, and amides, during demineralization, although it cannot be ruled out that some fraction of the missing C is in small grains that are difficult to recover from suspension, or in water‐soluble compounds trapped in phyllosilicates.  相似文献   

Depositional processes of impactites from the YAX-1 drill core in the Chicxulub impact structure inferred from vertical profiles of PDF orientations and grain size distributions of shocked quartz          下载免费PDF全文

Yu Chang  Kazuhisa Goto  Yasuhito Sekine  Eiichi Tajika 《Meteoritics & planetary science》2018,53(7):1323-1340

Core samples from the Chicxulub impact structure provide insights into the formation processes of a shallow-marine-target, complex crater. Although previous studies investigated the impactites (generally suevitic and polymict breccias) of the Yaxcopoil-1 (YAX-1) drill core in the Chicxulub impact structure, the interpretation of its deposition remains controversial. Here, we analyze planar deformation features (PDFs), grain size, and abundance of shocked quartz throughout the YAX-1 impactite sequence (794–895 m in depth). PDF orientations of most quartz grains in YAX-1 impactites show a distribution of both low angles ({104}, {103}, {102}) and high angles (orientations higher than 55° to c-axis), while the lower part of the impactite sequence contains quartz showing only PDF orientations of low angles. High-abundance, coarse-grained shocked quartz is found from the lower to middle parts of the impactites, whereas it abruptly changes to low-abundance, fine-grained shocked quartz within the upper part. In the uppermost part of the impactites, repeated oscillations in contents of these two components are observed. PDF orientation pattern suggests most of the shocked quartz grains experienced a range of shock pressure, except two samples in the lower part of impactites, which experienced only a high level of shock. We suggest that the base and lower part of the impactite sequence were formed by ejecta curtain and melt surge deposits, respectively. Our results are also consistent with the interpretation that the middle part of the impactite sequence is fallback ejecta from the impact plume. Additionally, we support the contention that massive seawater resurges into the crater occurred during the deposition of the upper and uppermost part of the impactites.  相似文献   

Human impacts on large benthic foraminifers near a densely populated area of Majuro Atoll, Marshall Islands     

Yoko Osawa  Yu Umezawa  Yoichi Ide  Toshihiro Miyajima 《Marine pollution bulletin》2010,60(8):1279-1287

Human impacts on sand-producing, large benthic foraminifers were investigated on ocean reef flats at the northeast Majuro Atoll, Marshall Islands, along a human population gradient. The densities of dominant foraminifers Calcarina and Amphistegina declined with distance from densely populated islands. Macrophyte composition on ocean reef flats differed between locations near sparsely or densely populated islands. Nutrient concentrations in reef-flat seawater and groundwater were high near or on densely populated islands. δ¹⁵N values in macroalgal tissues indicated that macroalgae in nearshore lagoons assimilate wastewater-derived nitrogen, whereas those on nearshore ocean reef flats assimilate nitrogen from other sources. These results suggest that increases in the human population result in high nutrient loading in groundwater and possibly into nearshore waters. High nutrient inputs into ambient seawater may have both direct and indirect negative effects on sand-producing foraminifers through habitat changes and/or the collapse of algal symbiosis.  相似文献   

Putting a spin on palaeotsunami deposits          下载免费PDF全文

James Goff  Bruce McFadgen  Catherine Chagué‐Goff  Kazuhisa Goto  Scott Nichol 《地球表面变化过程与地形》2016,41(9):1293-1296

Palaeotsunami research is a relatively young discipline and while considerable progress has been made in identifying the evidence of past events there are still difficulties on occasion in differentiating between palaeotsunami and palaeostorm deposits. This has tended to focus debate on the similarities and differences between deposits laid down by the two differing processes at the expense of alternative hypotheses. Although coastal research in New Zealand a decade ago drew attention to high elevation coarse sediment deposits laid down by waterspouts, it was largely ignored by the research community. Re‐analysis of a possible palaeotsunami deposit on a nearshore island in New Zealand, however, highlights the likelihood that this deposit, and perhaps many similar coastal ones, may have been laid down by waterspouts. In essence, the palaeotsunami–palaeostorm debate can no longer ignore waterspouts as an alternative hypothesis, but only time will tell how significant a contribution waterspouts have made to catastrophic coastal sedimentation. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Morphology and formation of spreading cracks on pillow lavas at Cape Grim, northwestern Tasmania, Australia     

Yoshihiko Goto  Jocelyn McPhie 《Bulletin of Volcanology》2012,74(7):1611-1619

Tertiary basaltic pillow lobes at Cape Grim, northwestern Tasmania, Australia display well-preserved spreading cracks in the glassy crust. The spreading cracks are lens-shaped or rectangular in plan view. In cross section, they consist of a graben-like depression with a broad floor bounded by steep scarps. The floor of spreading crack contains an axial crack and a number of ridges that are arranged symmetrically with respect to the axial crack. The ridges within spreading cracks are inferred to have formed by the regular, repeated production and splitting of new crust at the centre of the spreading crack. This new interpretation of ridges in spreading cracks differs from the previous interpretation in which they are regarded as elongate normal fault blocks. Our interpretation provides new insight into the propagation mechanisms of pillow lavas.  相似文献   

Integrated field spectroscopy of E+A (post-starburst) galaxies with the Kyoto tridimensional spectrograph II     

Tomotsugu Goto  Atsushi Kawai  Atsushi Shimono  Hajime Sugai  Masafumi Yagi  Takashi Hattori 《Monthly notices of the Royal Astronomical Society》2008,386(3):1355-1365

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Flocculation and particle size analysis of expansive clay sediments affected by biological, chemical, and hydrodynamic factors     

Xiaoling Tan  Liming Hu  Allen H. Reed  Yoko Furukawa  Guoping Zhang 《Ocean Dynamics》2014,64(1):143-157

Expansive clay sediments are abundant in riverine and estuarine waters and bottom beds, and their particle size distributions (PSD) are important for the analysis of sediment transport. This paper presents an experimental study to evaluate, using a laser particle size analyzer under varying flow conditions, the intrinsic PSD of two expansive clays, a Ca- and a Na-montmorillonite and the influence of biological, chemical, and hydrodynamic factors on their flocculation and PSD. The considered biological factor consists of three extracellular polymeric substances of varying polarity, including xanthan gum, guar gum, and chitosan; the chemical factor is the salinity; and the hydrodynamic factor is the types of flow indicated by the Reynolds number and shear rate. The intrinsic PSD of both clays show a multimodal lognormal distribution with sizes ranging from 0.2 to 50 μm. All three biopolymers, xanthan gum, guar gum, and chitosan, can facilitate flocculation through long-range polymer bridging and short-range ion-dipole interaction, hydrogen bonding, and Coulomb force. The influence of salinity is different for the two clays: the particle size of the Na-montmorillonite increases with salinity, which is caused by flocculation resulting from the suppressed electrical double layer, while that of the Ca-montmorillonite is slightly reduced owing to the decreased basal spacing and cation exchange. For different hydrodynamic conditions, higher shear rate promotes the flocculation of Ca-montmorillonite, but breaks the Na-montmorillonite flocs. The significance of understanding the flocculation and PSD of expansive clays is also discussed in terms of sediment transport under different aquatic environments.  相似文献